Methyl 2-(2-hydroxy-benzyl-ideneamino)-4,5,6,7-tetra-hydro-1-benzothio-phene-3-carboxyl-ate

Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 18;64(Pt 5):o869. doi: 10.1107/S1600536808010489.

Abstract

In the title compound, C(17)H(17)NO(3)S, the cyclohexene ring is essentially planar, with a maximum deviation of 0.006 (1) Å. The cyclo-hexene ring adopts a half-chair conformation. The dihedral angle between the thio-phene and benzene rings is 29.7 (1)°. The mol-ecular structure exhibits intra-molecular O-H⋯O, O-H⋯N and C-H⋯S hydrogen bonds, which generate one S(5) and two S(6) motifs. There is also a C-H⋯π inter-action between the cyclo-hexene ring system and the π-system of the benzene ring.