Bis[1,3-bis-(diphenyl-phosphino)propane-κP:P']silver(I) bis-(chloro-difluoro-acetato-κO)triphenyl-stannate(IV)

Yin Yin Teo; Kong Mun Lo; Seik Weng Ng

doi:10.1107/S1600536808010763

Bis[1,3-bis-(diphenyl-phosphino)propane-κP:P']silver(I) bis-(chloro-difluoro-acetato-κO)triphenyl-stannate(IV)

Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 23;64(Pt 5):m703. doi: 10.1107/S1600536808010763.

Authors

Yin Yin Teo¹, Kong Mun Lo, Seik Weng Ng

Affiliation

¹ Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

Abstract

In the title salt, [Ag(C(27)H(26)P(2))(2)][Sn(C(6)H(5))(3)(C(2)ClF(2)O(2))], the Ag(I) atom exists in a tetra-hedral coordination geometry formed by four P atoms [Ag-P = 2.460 (1)-2.501 (1) Å], whereas the Sn(IV) atom exists in a trans-trigonal-bipyramidal coordination geometry formed by two O [Sn-O = 2.208 (3) and 2.233 (3) Å] and three C atoms [Sn-C = 2.115 (4)-2.128 (4) Å;(Σ C-Sn-C)= 360.0 (6)°].