Bis{μ-N'-[1-(5-bromo-2-oxidophen-yl)ethyl-idene]benzene-sulfono-hydrazidato}-κO,N':N;κN:O,N'-bis-[(dimethyl sulfoxide-κO)copper(II)]

Hapipah M Ali; Musalem Laila; Razali M Rizal; Seik Weng Ng

doi:10.1107/S1600536808002201

Bis{μ-N'-[1-(5-bromo-2-oxidophen-yl)ethyl-idene]benzene-sulfono-hydrazidato}-κO,N':N;κN:O,N'-bis-[(dimethyl sulfoxide-κO)copper(II)]

Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 25;64(Pt 2):m414. doi: 10.1107/S1600536808002201.

Authors

Hapipah M Ali¹, Musalem Laila, Razali M Rizal, Seik Weng Ng

Affiliation

¹ Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

Abstract

In the title centrosymmetric dinuclear complex, [Cu(2)(C(15)H(11)BrN(2)O(3)S)(2)(C(2)H(6)OS)(2)], the Cu(II) ion is N,O-chelated by a dianionic ligand, monocoordinated by the sulfonamide N atom of a symmetry-related ligand and coordinated by an O atom from a dimethyl sulfoxide ligand, forming a distorted square-planar coordination geometry.