Di-μ-thio-cyanato-κN:N-bis-({2,4-di-bromo-6-[2-(methyl-amino)ethyl-imino-meth-yl]-phenol-ato-κN,N',O}nickel(II))

Hong-Wei Lin

doi:10.1107/S1600536807068146

Di-μ-thio-cyanato-κN:N-bis-({2,4-di-bromo-6-[2-(methyl-amino)ethyl-imino-meth-yl]-phenol-ato-κN,N',O}nickel(II))

Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 4;64(Pt 2):m295. doi: 10.1107/S1600536807068146.

Author

Hong-Wei Lin¹

Affiliation

¹ Department of Chemistry, Huaihua University, Huaihua 418008, People's Republic of China.

Abstract

The title complex, [Ni(2)(C(11)H(11)Br(2)N(2)O)(2)(NCS)(2)], is a thio-cyanate-bridged dinuclear nickel(II) complex. The asymmetric unit contains two molecules. Both Ni atoms in each molecule have a square-pyramidal coordination geometry, and each center is bound by one O and two N atoms of one Schiff base ligand and by one N atom of a bridging thio-cyanate ligand, which define the basal planes. N atoms from the bridging thio-cyanate ligands occupy the apical positions.