Bis[3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κO,N,N']copper(II) tetra-hydrate

Kai Zhao; Xian-Hong Yin; Fei-Long Hu; Cui-Wu Lin; Shang-Shang Zhang; Ru-Wen Qing

doi:10.1107/S1600536807068110

Bis[3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κO,N,N']copper(II) tetra-hydrate

Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 4;64(Pt 2):m284-5. doi: 10.1107/S1600536807068110.

Authors

Kai Zhao, Xian-Hong Yin, Fei-Long Hu, Cui-Wu Lin, Shang-Shang Zhang, Ru-Wen Qing

Abstract

In the title complex, [Cu(C(11)H(9)ClN(3)O(2))(2)]·4H(2)O, the Cu(II) atom is in a distorted octa-hedral coordination environment, coordinated by four N atoms and two O atoms from two tridentate 3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands. The mol-ecules are linked via inter-molecular O-H⋯O hydrogen bonds involving water mol-ecules to form extended chains along [010], and there are short Cl⋯Cl contacts [3.153 (4) Å].