{Bis[2-(dicyclo-hexyl-phosphino)phen-yl]methyl-silyl-κP,Si,P'}chloridoplatinum(II)

Yong-Hua Li; Yuan Zhang; Min-Min Zhao; Xian Li

doi:10.1107/S1600536808028857

{Bis[2-(dicyclo-hexyl-phosphino)phen-yl]methyl-silyl-κP,Si,P'}chloridoplatinum(II)

Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 17;64(Pt 10):m1272. doi: 10.1107/S1600536808028857.

Authors

Yong-Hua Li¹, Yuan Zhang, Min-Min Zhao, Xian Li

Affiliation

¹ Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, People's Republic of China.

Abstract

In the title compound, [Pt(C(37)H(55)P(2)Si)Cl], prepared from MeSiH[(cy)(2)PC(6)H(4)](2) and [Pt(cod)Cl(2)] (cy = cyclo-hexyl; cod = cyclo-octa-1,5-diene), the Pt(II) atom is coordinated by two P atoms, one Si atom and one Cl atom in a distorted square-planar geometry. The two P atoms are in a trans arrangement and the four cyclo-hexane rings adopt a chair conformation.