Tris[4-(2-pyridylmethyl-eneamino)phenol]iron(II) bis-(perchlorate)

Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 18;64(Pt 1):m212-3. doi: 10.1107/S1600536807066688.

Abstract

In the title compound, [Fe(C(12)H(10)N(2)O)(3)](ClO(4))(2), the metal center is coordinated by six N atoms from the three bidentate chelating ligands in a distorted octa-hedral coordination geometry, with overall formation of the meridional (OC-6-21) isomer. Inter-molecular O-H⋯O hydrogen bonds between the hydroxyl groups of the cation and the counter-anions form an infinite one-dimensional chain in the c-axis direction.