{Bis[2-(diphenyl-phosphan-yl)phen-yl] ether-κP,P'}(1,1'-dibenz-yl-1H,1'H-4,4'bi-1,2,3-triazole-κN,N)copper(I) hexa-fluorido-phosphate dichloro-methane hemisolvate

Uwe Monkowius; Stefan Ritter; Burkhard König; Hartmut Yersin; Manfred Zabel

doi:10.1107/S1600536807066342

{Bis[2-(diphenyl-phosphan-yl)phen-yl] ether-κP,P'}(1,1'-dibenz-yl-1H,1'H-4,4'bi-1,2,3-triazole-κN,N)copper(I) hexa-fluorido-phosphate dichloro-methane hemisolvate

Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 18;64(Pt 1):m195. doi: 10.1107/S1600536807066342.

Authors

Uwe Monkowius, Stefan Ritter, Burkhard König, Hartmut Yersin, Manfred Zabel

Abstract

In the crystal structure of the title compound, [Cu(C(18)H(16)N(6))(C(36)H(28)OP(2))]PF(6)·0.5CH(2)Cl(2) or [Cu(DPEPhos)(Bn-bta)]PF(6)·0.5CH(2)Cl(2) {DPEPhos = bis-[(diphenyl-phosphan-yl)phen-yl] ether and Bn-bta = 1,1'-dibenzyl-1H,1'H-4,4'-bi-1,2,3triazol-e}, the Cu atom is coordinated by two N and two P atoms of the ligands in a strongly distorted tetra-hedral environment. There are two crystallographically independent complex cations present, which differ significantly in their geometrical parameters. The solvent molecule is disordered but satisfactory atomic positions could not be determined.