Phosphorus fractions, sorption characteristics, and its release in the sediments of Baiyangdian Lake, China

Environ Monit Assess. 2011 Aug;179(1-4):335-45. doi: 10.1007/s10661-010-1740-9. Epub 2010 Oct 27.

Abstract

Sediment phosphorus (P) fractions and sorption characteristics and P release from intact sediment cores of Baiyangdian Lake in North China in spring 2009 were investigated. Results of chemical fractionation showed that total P (TP) content in sediment ranged from 443 to 611 mg kg( -1). Of the P fractions including inorganic P (IP) and organic P (OP), IP was a dominant component of TP and present in the form of P bounded to calcium (Ca-P) while the bioavailable P content bounded to Al, Fe, and Mn oxides and hydroxides (Fe/Al-P) varied from 14 to 102 mg kg( -1). The batch experiments showed that the sediments had appreciable maximum P adsorption capacity from 141.86 to 377.37 mg kg( -1). However, the zero P equilibrium concentration (C⁰(eq))in most sampling sites was larger than the P concentration in water column. Accordingly, the sediments from those sampling sites would release P into the overlying water at the positive P flux rates as a P release source. Significant positive correlation between P flux rates and Fe/Al-P revealed that the sediment P release would mainly originate from the bioavailable P fraction. It is evident that the inherent phosphorus present in lake sediments would be a major threat to the water quality and ecosystem reservation in Baiyangdian lake.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adsorption
  • China
  • Environmental Monitoring
  • Fresh Water / chemistry*
  • Geologic Sediments / chemistry*
  • Phosphorus / analysis*
  • Phosphorus / chemistry
  • Water Pollutants, Chemical / analysis*
  • Water Pollutants, Chemical / chemistry

Substances

  • Water Pollutants, Chemical
  • Phosphorus