Abstract
Well-defined dimeric or polymeric Pd(0) complexes [Pd(μ-(iPr)PCHP)](n) (n = 2 or ∞) containing the bridging ligand α,α'-bis(diisopropylphosphino)-m-xylene ((iPr)PCHP) are produced under mild conditions when the cyclometallated PCP pincer complex ((iPr)PCP)Pd-OH reacts with methanol or isopropanol.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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2-Propanol / chemistry
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Crystallography, X-Ray
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Ligands
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Methanol / chemistry
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Models, Molecular
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Molecular Structure
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Organometallic Compounds / chemical synthesis*
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Organometallic Compounds / chemistry
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Oxidation-Reduction
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Palladium / chemistry*
Substances
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Ligands
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Organometallic Compounds
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Palladium
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2-Propanol
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Methanol