Abstract
A Co(II)-Cu(II) framework based on a paramagnetic metalloligand [Co(Tt)(2)] shows a permanent porosity with a record high surface area for magnetic MOFs as well as a reversible magnetic transformation between a paramagnetic-like state and a short-range magnetic order in the low-temperature regime upon solvation-desolvation cyclings.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Adsorption
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Borates / chemistry*
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Cobalt / chemistry*
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Copper / chemistry*
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Ligands
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Magnetics*
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Models, Molecular
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Organometallic Compounds / chemistry*
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Porosity
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Temperature
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Triazoles / chemistry*
Substances
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Borates
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Ligands
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Organometallic Compounds
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Triazoles
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Cobalt
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Copper