Magnetic metal-organic framework constructed from a paramagnetic metalloligand exhibiting a significant sorption and reversible magnetic conversions

Chem Commun (Camb). 2010 Dec 14;46(46):8779-81. doi: 10.1039/c0cc03540h. Epub 2010 Oct 20.

Abstract

A Co(II)-Cu(II) framework based on a paramagnetic metalloligand [Co(Tt)(2)] shows a permanent porosity with a record high surface area for magnetic MOFs as well as a reversible magnetic transformation between a paramagnetic-like state and a short-range magnetic order in the low-temperature regime upon solvation-desolvation cyclings.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adsorption
  • Borates / chemistry*
  • Cobalt / chemistry*
  • Copper / chemistry*
  • Ligands
  • Magnetics*
  • Models, Molecular
  • Organometallic Compounds / chemistry*
  • Porosity
  • Temperature
  • Triazoles / chemistry*

Substances

  • Borates
  • Ligands
  • Organometallic Compounds
  • Triazoles
  • Cobalt
  • Copper