Magnetic composite prepared from palm shell-based carbon and application for recovery of residual oil from POME

Abstract

Magnetic separation combined with adsorption by activated carbon has been found to be a useful method for removing pollutants. In this paper, the use of palm shell as a source of activated carbon for the removal and recovery of oil from palm oil mill effluent (POME) is studied. In the first part of the study, the properties of samples of activated carbon prepared from palm shell under a variety of different conditions were characterized for their hydrophobicity, surface areas and pore size distribution. The most effective of the activated carbon samples was prepared by impregnation with ZnCl(2) followed by combined physical/chemical activation under carbon dioxide flow at 800 °C. Four grams of these samples adsorbed 90% of the oil from 50 mL POME. In the second part, the palm shell-based carbon samples were given magnetic properties by the technique of iron oxide deposition. Ninety-four percent of the activated carbon/iron oxide composite containing the adsorbed oil could be extracted from the POME by a magnetic bar of 0.15 T. Four grams of the composite can remove 85% of oil from 50 mL POME and a total of 67% of the initial oil can then be recovered by hexane extraction. Powder X-ray diffractometry showed the presence of magnetite and maghemite in the activated carbon/iron oxide composite.