Synthesis, characterization and property of a mixed-valent Ag(I)/Ag(II) coordination polymer

Di Sun; Cheng-Feng Yang; Hao-Ran Xu; Hai-Xia Zhao; Zhan-Hua Wei; Na Zhang; La-Jia Yu; Rong-Bin Huang; Lan-Sun Zheng

doi:10.1039/c0cc02112a

Synthesis, characterization and property of a mixed-valent Ag(I)/Ag(II) coordination polymer

Chem Commun (Camb). 2010 Nov 21;46(43):8168-70. doi: 10.1039/c0cc02112a. Epub 2010 Sep 28.

Authors

Di Sun¹, Cheng-Feng Yang, Hao-Ran Xu, Hai-Xia Zhao, Zhan-Hua Wei, Na Zhang, La-Jia Yu, Rong-Bin Huang, Lan-Sun Zheng

Affiliation

¹ Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.

PMID: 20877842
DOI: 10.1039/c0cc02112a

Abstract

A novel mixed-valent Ag(I)/Ag(II) coordination polymer {[Ag(I)(2)Ag(II)(0.5)(SO(4))(HSO(4))(pyz)(2.5)]·H(2)O}(n) (1, pyz = pyrazine) was synthesized and characterized. The results show it presents semiconducting and photoluminescent properties.