Temperature- and electric-field-induced inverse Freedericksz transition in a nematogen with weak surface anchoring

Phys Rev E Stat Nonlin Soft Matter Phys. 2010 Jul;82(1 Pt 1):011701. doi: 10.1103/PhysRevE.82.011701. Epub 2010 Jul 2.

Abstract

We report electric field dependence of the anchoring transition in a mesogen on cooling in a cell with perfluoropolymer treated surfaces. Below a crossover voltage V(co) the transition is discontinuous between planar and homeotropic alignments, and as the temperature is lowered, the transition temperature decreases quadratically with the field. Above V(co) the transition is continuous between planar and tilted alignments, the transition temperature decreasing essentially linearly with the rms field. We develop a simple model to account for these results and argue that the higher field regime corresponds to a temperature driven inverse Freedericksz transition in which the director orientation starts tilting at the weakly anchored surfaces while the tilt angle remains zero at the midplane of the cell.