Statistical mechanics far from equilibrium: prediction and test for a sheared system

Phys Rev E Stat Nonlin Soft Matter Phys. 2010 May;81(5 Pt 1):051109. doi: 10.1103/PhysRevE.81.051109. Epub 2010 May 10.

Abstract

We report the application of a far-from-equilibrium statistical-mechanical theory to a nontrivial system with Newtonian interactions in continuous boundary-driven flow. By numerically time stepping the force-balance equations of a one-dimensional model fluid we measure occupancies and transition rates in simulation. The high-shear-rate simulation data reproduce the predicted invariant quantities, thus supporting the theory that a class of nonequilibrium steady states of matter, namely, sheared complex fluids, is amenable to statistical treatment from first principles.