Abstract
Water-soluble phosphanes were tagged with a light-responding diazo group. Upon UV exposure, the diazo-isomerisation led to phosphane morphology change, resulting in an increase in the reaction rate of an aqueous palladium-catalysed cleavage reaction.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Catalysis
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Hydrophobic and Hydrophilic Interactions*
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Isomerism
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Organometallic Compounds / chemistry*
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Phosphines / chemistry*
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Photochemical Processes*
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Water / chemistry*
Substances
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Organometallic Compounds
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Phosphines
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Water
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phosphine