Abstract
The synthesis of a monosilylated Grubbs-Hoveyda ruthenium alkylidene complex is described, as well as the preparation and characterization of the corresponding material by sol-gel cogelification with tetraethoxysilane (TEOS) and the assay of this recyclable supported catalyst in ring-closing diene and enyne metathesis reactions under thermal and microwave conditions.
Publication types
-
Research Support, Non-U.S. Gov't
MeSH terms
-
Catalysis
-
Cyclization
-
Magnetic Resonance Spectroscopy
-
Methane / analogs & derivatives*
-
Methane / chemistry
-
Microwaves
-
Models, Chemical*
-
Nitrogen / chemistry
-
Organic Chemicals / chemistry*
-
Porosity
-
Ruthenium / chemistry*
-
Silicon Dioxide / chemical synthesis
-
Silicon Dioxide / chemistry*
-
Temperature
Substances
-
Organic Chemicals
-
carbene
-
Silicon Dioxide
-
Ruthenium
-
Nitrogen
-
Methane