Definite coordination arrangement of organometallic palladium complexes accumulated on the designed interior surface of apo-ferritin

Ziyue Wang; Yusuke Takezawa; Hiroki Aoyagi; Satoshi Abe; Tatsuo Hikage; Yoshihito Watanabe; Susumu Kitagawa; Takafumi Ueno

doi:10.1039/c0cc02221g

Definite coordination arrangement of organometallic palladium complexes accumulated on the designed interior surface of apo-ferritin

Chem Commun (Camb). 2011 Jan 7;47(1):170-2. doi: 10.1039/c0cc02221g. Epub 2010 Aug 23.

Authors

Ziyue Wang¹, Yusuke Takezawa, Hiroki Aoyagi, Satoshi Abe, Tatsuo Hikage, Yoshihito Watanabe, Susumu Kitagawa, Takafumi Ueno

Affiliation

¹ Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Nagoya, 464-8602, Japan.

PMID: 20730233
DOI: 10.1039/c0cc02221g

Abstract

Apo-ferritin (apo-Fr) mutants are used as scaffolds to accommodate palladium (allyl) complexes. Various coordination arrangements of the Pd complexes are achieved by adjusting the positions of cysteine and histidine residues on the interior surface of the apo-Fr cage.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Animals
Apoferritins / chemistry*
Apoferritins / genetics
Apoferritins / metabolism
Crystallography, X-Ray
Horses
Models, Molecular
Mutation
Organometallic Compounds / chemical synthesis
Organometallic Compounds / chemistry*
Organometallic Compounds / metabolism
Palladium / chemistry*
Surface Properties

Substances

Organometallic Compounds
Palladium
Apoferritins

Associated data

PDB/3NOZ
PDB/3NP0
PDB/3NP2