Gold(I) "click" 1,2,3-triazolylidenes: synthesis, self-assembly and catalysis

Kelly J Kilpin; Ursula S D Paul; Ai-Lan Lee; James D Crowley

doi:10.1039/c0cc02185g

Gold(I) "click" 1,2,3-triazolylidenes: synthesis, self-assembly and catalysis

Chem Commun (Camb). 2011 Jan 7;47(1):328-30. doi: 10.1039/c0cc02185g. Epub 2010 Aug 23.

Authors

Kelly J Kilpin¹, Ursula S D Paul, Ai-Lan Lee, James D Crowley

Affiliation

¹ Department of Chemistry, University of Otago, PO Box 56, Dunedin, New Zealand.

PMID: 20730214
DOI: 10.1039/c0cc02185g

Abstract

Novel gold(I) "click" carbene(1,2,3-triazolylidene) complexes have been synthesised, characterised and exploited for the self-assembly of a metallomacrocycle and as precatalysts for gold(I)-catalysed reactions.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Catalysis
Click Chemistry
Crystallography, X-Ray
Gold / chemistry*
Ligands
Methane / analogs & derivatives
Methane / chemistry
Models, Molecular
Molecular Structure
Organogold Compounds / chemical synthesis*
Organogold Compounds / chemistry*

Substances

Ligands
Organogold Compounds
carbene
Gold
Methane