Polymeric ligands as homogeneous, reusable catalyst systems for copper assisted click chemistry

Chem Commun (Camb). 2010 Dec 14;46(46):8719-21. doi: 10.1039/c0cc01451f. Epub 2010 Aug 20.

Abstract

Tris-(benzyltriazolylmethyl)amine (TBTA) has been immobilized onto a styrenic monomer and subsequently copolymerized with styrene to afford catalytically active and reusable copolymers for the CuAAC reaction.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alkynes / chemistry*
  • Azides / chemical synthesis*
  • Azides / chemistry*
  • Catalysis
  • Click Chemistry*
  • Copper / chemistry*
  • Cyclization
  • Ligands
  • Molecular Structure
  • Organometallic Compounds / chemical synthesis
  • Organometallic Compounds / chemistry*
  • Polymers / chemical synthesis
  • Polymers / chemistry*
  • Styrene / chemistry

Substances

  • Alkynes
  • Azides
  • Ligands
  • Organometallic Compounds
  • Polymers
  • Styrene
  • Copper