Abstract
Chiral cyclic alpha-amino acid containing oligopeptide catalyzed highly enantioselective epoxidation of alpha,beta-unsaturated ketones and the alpha-helical secondary structure of the peptide catalyst were revealed by X-ray crystallographic analysis.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Catalysis
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Combinatorial Chemistry Techniques
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Crystallography, X-Ray
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Epoxy Compounds / chemical synthesis*
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Epoxy Compounds / chemistry
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Ketones / chemistry*
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Molecular Conformation
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Peptides / chemical synthesis
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Peptides / chemistry*
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Protein Structure, Secondary
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Stereoisomerism
Substances
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Epoxy Compounds
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Ketones
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Peptides