Adsorption study of 14C-paraquat in two Malaysian agricultural soils

Environ Monit Assess. 2011 May;176(1-4):43-50. doi: 10.1007/s10661-010-1565-6. Epub 2010 Jun 29.

Abstract

The adsorption equilibrium time and effects of pH and concentration of (14)C-labeled paraquat (1,1(')-dimethyl-4,4(')-bipyridylium dichloride) in two types of Malaysian soil were investigated. The soils used in the study were clay loam and clay soils from rice fields. Equilibrium studies of paraquat in a soil and pesticide solution were conducted. Adsorption equilibrium time was achieved within 2 h for both soil types. The amount of (14)C-labeled paraquat adsorbed onto glass surfaces increased with increasing shaking time and remained constant after 10 h. It was found that paraquat adsorbed by the two soils was very similar: 51.73 (clay loam) and 51.59 μ g g(-1) (clay) at 1 μ g/ml. The adsorption of paraquat onto both types of soil was higher at high pH, and adsorption decreased with decreasing pH. At pH 11, the amounts of (14)C-labeled paraquat adsorbed onto the clay loam and clay soil samples were 4.08 and 4.05 μ g g(-1), respectively, whereas at pH 2, the amounts adsorbed were 3.72 and 3.57 μ g g(-1), respectively. Results also suggested that paraquat sorption by soil is concentration dependent.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adsorption
  • Agriculture*
  • Hydrogen-Ion Concentration
  • Paraquat / analysis*
  • Paraquat / chemistry*
  • Soil Pollutants / analysis*
  • Soil Pollutants / chemistry*

Substances

  • Soil Pollutants
  • Paraquat