Abstract
The reaction of vanadocene dichloride with sodium arsenate gives Cp(2)V(O(2)AsO(2)H). This compound was identified on the basis of the super-hyperfine coupling observed in the solution EPR spectrum. The effect of substitution was studied on the ring-substituted and ansa-bridged compounds.
Copyright (c) 2010 John Wiley & Sons, Ltd.
Publication types
-
Research Support, Non-U.S. Gov't
MeSH terms
-
Arsenates / chemistry*
-
Coordination Complexes* / chemical synthesis
-
Coordination Complexes* / chemistry
-
Cyclopentanes / chemistry
-
Electron Spin Resonance Spectroscopy / methods*
-
Solutions
-
Vanadium Compounds / chemistry*
Substances
-
Arsenates
-
Coordination Complexes
-
Cyclopentanes
-
Solutions
-
Vanadium Compounds
-
vanadocene dichloride
-
sodium arsenate