Abstract
Syntheses of the bimetallic uranium(III) and neptunium(III) complexes [(UI)(2)(L)], [(NpI)(2)(L)], and [{U(BH(4))}(2)(L)] of the Schiff-base pyrrole macrocycles L are described. In the absence of single-crystal structural data, fitting of the variable-temperature solid-state magnetic data allows the prediction of polymeric structures for these compounds in the solid state.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Ligands
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Macrocyclic Compounds / chemical synthesis*
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Macrocyclic Compounds / chemistry
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Magnetics*
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Molecular Structure
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Neptunium / chemistry*
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Organometallic Compounds / chemical synthesis*
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Organometallic Compounds / chemistry
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Temperature
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Uranium / chemistry*
Substances
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Ligands
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Macrocyclic Compounds
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Organometallic Compounds
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Uranium
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Neptunium