The first nonaselenium ring

Pavlo Yu Demchenko; Roman E Gladyshevskii; Sergei V Volkov; Oleg G Yanko; Lyudmila B Kharkova; Zoya A Fokina; Andrey A Fokin

doi:10.1039/c0cc00192a

The first nonaselenium ring

Chem Commun (Camb). 2010 Jul 7;46(25):4520-2. doi: 10.1039/c0cc00192a. Epub 2010 May 11.

Authors

Pavlo Yu Demchenko¹, Roman E Gladyshevskii, Sergei V Volkov, Oleg G Yanko, Lyudmila B Kharkova, Zoya A Fokina, Andrey A Fokin

Affiliation

¹ Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla i Mefodiya str. 6, UA-79005 Lviv, Ukraine.

PMID: 20461238
DOI: 10.1039/c0cc00192a

Abstract

The reaction of Se(2)Cl(2) with RhCl(3).4H(2)O at 100 degrees C gives dirhodium nonaselenium hexachloride Rh(2)Se(9)Cl(6). The structure exhibits the first Se(9) ring observed to date.