Highly luminescent bis-cyclometalated iridium(III) ethylenediamine complex: synthesis and correlation between the solid state polymorphism and the photophysical properties

Anna Maria Talarico; Iolinda Aiello; Anna Bellusci; Alessandra Crispini; Mauro Ghedini; Nicolas Godbert; Teresa Pugliese; Elisabeta Szerb

doi:10.1039/b925471b

Highly luminescent bis-cyclometalated iridium(III) ethylenediamine complex: synthesis and correlation between the solid state polymorphism and the photophysical properties

Dalton Trans. 2010 Feb 21;39(7):1709-12. doi: 10.1039/b925471b. Epub 2010 Jan 5.

Authors

Anna Maria Talarico¹, Iolinda Aiello, Anna Bellusci, Alessandra Crispini, Mauro Ghedini, Nicolas Godbert, Teresa Pugliese, Elisabeta Szerb

Affiliation

¹ Centro di Eccellenza CEMIF.CAL, LASCAMM CR-INSTM and Laboratorio Regionale Licryl, CNR-INFM, Dipartimento di Chimica, Università della Calabria, 87030 Arcavacata di Rende, Italy.

PMID: 20449409
DOI: 10.1039/b925471b

Abstract

The solvent induced polymorphism observed in a cyclometalated iridium(iii) ethylenediamine ionic complex is a new tool to modulate and enhance emission in the solid crystalline state.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Crystallography, X-Ray
Iridium / chemistry*
Luminescence*
Models, Molecular
Organometallic Compounds / chemistry*
Photochemistry
Solvents / chemistry

Substances

Organometallic Compounds
Solvents
Iridium