Latent olefin metathesis catalysts

Chem Soc Rev. 2009 Dec;38(12):3360-72. doi: 10.1039/b902345n. Epub 2009 Sep 23.

Abstract

Olefin metathesis is a versatile synthetic tool for the redistribution of alkylidene fragments at carbon-carbon double bonds. This field, and more specifically the development of task-specific, latent catalysts, attracts emerging industrial and academic interest. This tutorial review aims to provide the reader with a concise overview of early breakthroughs and recent key developments in the endeavor to develop latent olefin metathesis catalysts, and to illustrate their use by prominent examples from the literature.

Publication types

  • Research Support, Non-U.S. Gov't
  • Review

MeSH terms

  • Alkenes / chemistry*
  • Catalysis
  • Molecular Conformation
  • Organometallic Compounds / chemical synthesis
  • Organometallic Compounds / chemistry*
  • Ruthenium / chemistry*
  • Stereoisomerism

Substances

  • Alkenes
  • Organometallic Compounds
  • Ruthenium