Polyoxometalate-supported Pd nanoparticles as efficient catalysts for the direct synthesis of hydrogen peroxide in the absence of acid or halide promoters

Miao Sun; Jizhe Zhang; Qinghong Zhang; Ye Wang; Huilin Wan

doi:10.1039/b910317a

Polyoxometalate-supported Pd nanoparticles as efficient catalysts for the direct synthesis of hydrogen peroxide in the absence of acid or halide promoters

Chem Commun (Camb). 2009 Sep 14:(34):5174-6. doi: 10.1039/b910317a. Epub 2009 Jul 21.

Authors

Miao Sun¹, Jizhe Zhang, Qinghong Zhang, Ye Wang, Huilin Wan

Affiliation

¹ State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.

PMID: 20448984
DOI: 10.1039/b910317a

Abstract

A Keggin-type polyoxometalate (Cs(1.5)H(1.5)PW(12)O(40))-supported Pd catalyst is efficient for the direct synthesis of H(2)O(2) from H(2) and O(2) in the absence of any acid or halide additives under atmospheric pressure.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Catalysis
Hydrogen Peroxide / chemical synthesis*
Hydrogen Peroxide / chemistry
Metal Nanoparticles / chemistry*
Organometallic Compounds / chemistry*
Palladium / chemistry*
Tungsten Compounds / chemistry*

Substances

Organometallic Compounds
Tungsten Compounds
polyoxometalate I
Palladium
Hydrogen Peroxide