A NbO-type metal-organic framework derived from a polyyne-coupled di-isophthalate linker formed in situ

Dan Zhao; Daqiang Yuan; Andrey Yakovenko; Hong-Cai Zhou

doi:10.1039/c002767g

A NbO-type metal-organic framework derived from a polyyne-coupled di-isophthalate linker formed in situ

Chem Commun (Camb). 2010 Jun 21;46(23):4196-8. doi: 10.1039/c002767g. Epub 2010 May 6.

Authors

Dan Zhao¹, Daqiang Yuan, Andrey Yakovenko, Hong-Cai Zhou

Affiliation

¹ Department of Chemistry, Texas A&M University, PO Box 30012, College Station, TX 77842, USA.

PMID: 20448879
DOI: 10.1039/c002767g

Abstract

A NbO-type metal-organic framework, PCN-46, was constructed based on a polyyne-coupled di-isophthalate linker formed in situ. Its lasting porosity was confirmed by N(2) adsorption isotherm, and its H(2), CH(4) and CO(2) adsorption capacity was examined at 77 K and 298 K over a wide pressure range (0-110 bar).