A feasible way to manipulate the scales of Ag wires through the polyol process is presented. By adjusting the amounts of either Pd or Ag precursor used in this process, we demonstrated the ability to control the scale of the wires. The presence of Pd ultrafine particles reduced by EG in advance served as the nuclei for inducing the subsequent formation of Ag wires, and the diameter of the resulting wires was observed to be inversely proportional to the quantity of Pd added. Further, the wire length was demonstrated to be proportional to and highly correlated with the total amount of Ag added, by a linear relationship. A glass plate coated with Ag wire film by the spray method is shown to be both transparent and conductive. The effect of scaling the wires on their performance is also discussed.