Boron-nitrogen analogues of the fluorenyl anion

Dalton Trans. 2010 Jun 7;39(21):5084-6. doi: 10.1039/c0dt00028k.

Abstract

The synthesis and structural characterisation of [BPh(bipy)] and [BCl(bipy)] are described both of which contain a direduced bipy ligand (bipy = 2,2'-bipyridyl) and are analogues of the fluorenyl anion; DFT calculations highlight differences in the electronic structure of both species compared to the fluorenyl anion.