Abstract
The title complexes catalyze the aerobic oxidations of hydrocarbons using visible light and atmospheric oxygen as oxygen source in sequences employing photodisproportionation reactions. The putative oxidants, ruthenium(V)-oxo porphyrin species, can be detected and studied in real time via laser flash photolysis methods.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Aerobiosis
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Alkenes / chemistry*
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Catalysis
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Dimerization
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Light
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Metalloporphyrins / chemistry*
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Molecular Structure
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Oxidation-Reduction
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Photochemistry
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Photolysis
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Ruthenium / chemistry*
Substances
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Alkenes
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Metalloporphyrins
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Ruthenium