Preparation and characterization of self-cleaning glass for vehicle with niobia nanosheets

ACS Appl Mater Interfaces. 2010 Apr;2(4):1236-41. doi: 10.1021/am100091f.

Abstract

Self-cleaning glasses were prepared by coating niobia nanosheets and investigated on the performance. The coated glass heated at >450 degrees C had very low turbidity, high hardness, and excellent adhesion properties. Niobia nanosheets ([Nb(3)O(8)](-)) reacted with sodium ions (Na(+)) diffused from the glass into the films to form a crystalline phase of NaNb(3)O(8) and this phase was converted to NaNbO(3) at >450 degrees C. The films exhibited photoinduced hydrophilicity under UV irradiation but low photocatalytic oxidation activity. Excellent self-cleaning ability of the niobia nanosheet coated glass was confirmed by the Taber abrasion test, which is thought to be a candidate as self-cleaning glasses for vehicles.

MeSH terms

  • Adhesiveness
  • Catalysis
  • Glass*
  • Hardness
  • Hot Temperature
  • Ions
  • Microscopy, Electron, Scanning / methods
  • Nanostructures / chemistry*
  • Nanotechnology / methods*
  • Niobium / chemistry*
  • Oxygen / chemistry
  • Photochemistry / methods
  • Sodium / chemistry
  • Temperature

Substances

  • Ions
  • Niobium
  • Sodium
  • Oxygen