Gap structure effects on surface-enhanced Raman scattering intensities for gold gapped rods

Nano Lett. 2010 May 12;10(5):1722-7. doi: 10.1021/nl100099g.

Abstract

Gapped rods provide a unique platform for elucidating structure/function relationships, both for single-molecule electrochemical techniques and for surface-enhanced Raman scattering (SERS). This paper attempts to elucidate the dependence of SERS intensities on gap topography and gap distance for gold gapped rods with segment lengths varying over a wide range (40-2000 nm). Significantly, we have determined that rough gaps lead to a smaller SERS enhancement than smooth gaps for these structures even though the rough gaps have a larger total surface area. Both theory and experiment show periodic variation of SERS intensity with segment length as determined by odd-symmetry plasmon multipoles. Excitation of even-symmetry modes is dipole forbidden (for polarization along the rod axis), but this selection rule can be relaxed by roughness or, for smooth gaps, by near-field coupling between the rod segments.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Computer Simulation
  • Gold / chemistry*
  • Models, Chemical*
  • Nanostructures / chemistry*
  • Nanostructures / ultrastructure*
  • Scattering, Radiation
  • Surface Plasmon Resonance / methods*

Substances

  • Gold