Two dicobalt(III) complexes of triazolate-containing [2+2] Schiff-base macrocycles coordinate thiocyanate ions via the sulfur atom

Dalton Trans. 2010 Apr 14;39(14):3358-60. doi: 10.1039/b925745d. Epub 2010 Feb 15.

Abstract

Highly unusual S-coordination modes are observed for the four axial thiocyanate co-ligands in two structurally characterised dicobalt(iii) [2+2] triazolate-based macrocyclic complexes.