Natural abundance solid-state 95Mo MAS NMR of MoS2 reveals precise 95Mo anisotropic parameters from its central and satellite transitions

Hans J Jakobsen; Henrik Bildsøe; Jørgen Skibsted; Michael Brorson; Kjeld Schaumburg

doi:10.1039/b926699b

Natural abundance solid-state 95Mo MAS NMR of MoS2 reveals precise 95Mo anisotropic parameters from its central and satellite transitions

Chem Commun (Camb). 2010 Mar 28;46(12):2103-5. doi: 10.1039/b926699b. Epub 2010 Feb 9.

Authors

Hans J Jakobsen¹, Henrik Bildsøe, Jørgen Skibsted, Michael Brorson, Kjeld Schaumburg

Affiliation

¹ Instrument Centre for Solid-State NMR Spectroscopy, Interdisciplinary Nanoscience Center (iNANO), Department of Chemistry, Aarhus University, DK-8000 Aarhus C, Denmark. hja@chem.au.dk

PMID: 20221506
DOI: 10.1039/b926699b

Abstract

Precise values are reported for a quite large (95)Mo quadrupole coupling and an unusually large (95)Mo chemical shift anisotropy in MoS(2), values that have been retrieved by analysis of a well-resolved, highly complex 14.1 T (95)Mo MAS NMR spectrum displaying both the central and satellite transitions.