Abstract
The first exo-selective asymmetric 1,3-dipolar cycloaddition of alkylidene malonates with azomethine ylides catalyzed by AgOAc/TF-BiphamPhos has been reported in good yields and good to excellent enantio-/diastereoselectivities.
Publication types
-
Research Support, Non-U.S. Gov't
MeSH terms
-
Acetates / chemistry*
-
Azo Compounds / chemistry*
-
Catalysis
-
Coordination Complexes / chemistry*
-
Malonates / chemistry*
-
Silver Compounds / chemistry*
-
Stereoisomerism
-
Substrate Specificity
-
Thiosemicarbazones / chemistry*
Substances
-
Acetates
-
Azo Compounds
-
Coordination Complexes
-
Malonates
-
Silver Compounds
-
TF-BiphamPhos
-
Thiosemicarbazones
-
azomethine
-
silver acetate
-
malonic acid