The recent results reported in reference 1 have produced an increased interest in explaining deviations from the ideal behavior of the energetic variation of the diffraction efficiency of holographic gratings. This ideal behavior occurs when uniform gratings are recorded, and the index modulation is proportional to the energetic exposure. As a result, a typical sin(2) curve is obtained reaching a maximum diffraction efficiency and saturation at or below this value. However, linear deviations are experimentally observed when the first maximum on the curve is lower than the second. This effect does not correspond to overmodulation and recently in PVA/acrylamide photopolymers of high thickness it has been explained by the dye concentration in the layer and the resulting molecular weight of the polymer chains generated in the polymerization process. In this work, new insights into these deviations are gained from the analysis of the non-uniform gratings recorded. Therefore, we show that deviations from the linear response can be explained by taking into account the energetic evolution of the index modulation as well as the fringe bending in the grating.