Abstract
Readily synthesised mono- and di- 1,4-substituted-1,2,3-triazole "click" ligands are shown to self-assemble into discrete metallocyclic architectures with Ag(I) ions. The silver metallomacrocycles are stable in solution and the solid state and have been fully characterised by elemental analysis, HR-ESMS, IR, (1)H and (13)C NMR and in three cases the structures were confirmed by X-ray crystallography.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Crystallography, X-Ray
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Ligands
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Macrocyclic Compounds / chemical synthesis
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Macrocyclic Compounds / chemistry
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Models, Molecular
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Molecular Structure
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Organometallic Compounds / chemical synthesis*
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Organometallic Compounds / chemistry
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Silver / chemistry*
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Stereoisomerism
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Triazoles / chemistry*
Substances
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Ligands
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Macrocyclic Compounds
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Organometallic Compounds
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Triazoles
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Silver