Hydrodynamic effects on chiral induction

Chem Soc Rev. 2010 Feb;39(2):569-77. doi: 10.1039/b916369g. Epub 2009 Oct 20.

Abstract

There are few unambiguous reports describing the transfer of chirality from stirring vortices down to the level of electronic transitions. In this tutorial review the methods reported are discussed as well as the structural trends that seem to be necessary conditions in order to detect this phenomenon.

Publication types

  • Research Support, Non-U.S. Gov't
  • Review

MeSH terms

  • Circular Dichroism
  • Molecular Conformation
  • Porphyrins / chemistry*
  • Stereoisomerism

Substances

  • Porphyrins
  • tetraphenylporphine sulfonate