'Super-reduced' iron under physiologically-relevant conditions

Dalton Trans. 2010 Feb 14;39(6):1464-6. doi: 10.1039/b919517c. Epub 2009 Dec 9.

Abstract

EPR spectroscopy is employed to demonstrate chemical production of formally Fe(i) and Fe(0) states of phthalocyanines in water at room temperature, and physiologically-relevant pH.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Electron Spin Resonance Spectroscopy
  • Hydrogen-Ion Concentration
  • Indoles / chemistry
  • Iron / chemistry*
  • Isoindoles
  • Spectrophotometry, Ultraviolet
  • Temperature
  • Water / chemistry

Substances

  • Indoles
  • Isoindoles
  • Water
  • Iron
  • phthalocyanine