Abstract
By modifying the mouth of a macrocyclic dicobalt Pacman complex, it is possible to both isolate new bridging-superoxo and hydroxyl complexes and to tune the reactivity of this system towards catalytic four-electron reduction of dioxygen to water.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Catalysis
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Cobalt / chemistry*
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Macrocyclic Compounds / chemistry
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Molecular Structure
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Organometallic Compounds / chemistry*
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Oxidation-Reduction
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Oxygen / chemistry*
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Pyrroles / chemistry*
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Schiff Bases / chemistry
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Water / chemistry
Substances
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Macrocyclic Compounds
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Organometallic Compounds
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Pyrroles
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Schiff Bases
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Water
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Cobalt
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Oxygen