Vanadium(II) heptacyanomolybdate(III)-based magnet exhibiting a high curie temperature of 110 K

Keisuke Tomono; Yoshihide Tsunobuchi; Koji Nakabayashi; Shin-Ichi Ohkoshi

doi:10.1021/ic9022079

Vanadium(II) heptacyanomolybdate(III)-based magnet exhibiting a high curie temperature of 110 K

Inorg Chem. 2010 Feb 15;49(4):1298-300. doi: 10.1021/ic9022079.

Authors

Keisuke Tomono¹, Yoshihide Tsunobuchi, Koji Nakabayashi, Shin-Ichi Ohkoshi

Affiliation

¹ Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Toyko 113-0033, Japan.

PMID: 20078097
DOI: 10.1021/ic9022079

Abstract

We prepared a vanadium heptacyanomolybdate-based magnet, V(II)(2)[Mo(III)(CN)(7)].(pyrimidine)(2).4.5H(2)O (VMo), with a Curie temperature (T(C)) of 110 K, which is the highest T(C) value in [Mo(III)(CN)(7)]-based magnets. Additionally, Mn(II)(2)[Mo(III)(CN)(7)].(pyrimidine)(2).2H(2)O (MnMo) of a monoclinic structure (P2(1)/n) with T(C) = 47 K was prepared to confirm the crystal structure of VMo.