Abstract
Short and efficient access to (+)-lupinine and (+)-epiquinamide by means of an unprecedented double hydroformylation of a bis-homoallylic azide followed by a tandem catalytic hydrogenation/reductive bis-amination is reported.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alkaloids / chemical synthesis*
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Alkaloids / chemistry
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Amination
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Azides / chemistry
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Catalysis
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Hydrogenation
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Molecular Structure
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Quinolizines / chemical synthesis*
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Quinolizines / chemistry
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Sparteine / analogs & derivatives*
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Sparteine / chemical synthesis
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Sparteine / chemistry
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Stereoisomerism
Substances
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Alkaloids
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Azides
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Quinolizines
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epiquinamide
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Sparteine
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lupinine