Heterometallic 3d-4f polyoxometalate derived from the weakley-type dimeric structure

Santiago Reinoso; José Ramón Galán-Mascarós

doi:10.1021/ic902217g

Heterometallic 3d-4f polyoxometalate derived from the weakley-type dimeric structure

Inorg Chem. 2010 Jan 18;49(2):377-9. doi: 10.1021/ic902217g.

Authors

Santiago Reinoso¹, José Ramón Galán-Mascarós

Affiliation

¹ Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, Polígono de La Coma s/n, E-46980 Paterna, Valencia, Spain. santiago.reinoso@uv.es

PMID: 20000715
DOI: 10.1021/ic902217g

Abstract

Polyanion [{Ce(H(2)O)(2)}(2)Mn(2)(B-alpha-GeW(9)O(34))(2)](8-) (1) constitutes the first example of a heterometallic 3d-4f cluster related to the Weakley-type dimeric structure, and it contains an unprecedented Ce(III)(2)Mn(III)(2)O(20) rhomblike moiety displaying dominant Ce(III)-Mn(III) ferromagnetic interactions.