Poly[bis(mu3-5'-carboxy-2,2'-bipyridine-5-carboxylato-kappa4O:N,N':O')lead(II)]

Acta Crystallogr C. 2009 Dec;65(Pt 12):m491-3. doi: 10.1107/S0108270109047015. Epub 2009 Nov 25.

Abstract

The title compound, [Pb(C(12)H(7)N(2)O(4))(2)](n), obtained by reaction of Pb(NO(3))(2) and 2,2'-bipyridine-5,5'-dicarboxylic acid (H(2)bptc) under hydrothermal conditions, has a structure in which the unique Pb(II) cation sits on a twofold axis and is octa-coordinated by four O-atom donors from four Hbptc(-) ligands and four N-atom donors from two Hbptc(-) ligands in a distorted dodecahedral geometry. With each Pb(II) cation connected to six Hbptc(-) ligands and each Hbptc(-) ligand bridging three Pb(II) cations, a three-dimensional polymeric structure is formed. From a topological point of view, the three-dimensional net is binodal, with six-connected (the Pb(II) cation) and three-connected (the Hbptc(-) ligand) nodes, resulting in a distorted rutile (4(2).8)(2)(4(4)8(9)12(2)) topology.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Cations
  • Crystallography, X-Ray
  • Ligands
  • Models, Molecular
  • Organometallic Compounds / chemistry*
  • Polymers

Substances

  • Cations
  • Ligands
  • Organometallic Compounds
  • Polymers
  • poly(bis(mu3-5'-carboxy-2,2'-bipyridine-5-carboxylato-kappa4O-N,N'-O')lead(II))