Orientational ordering of solution derived epitaxial Gd-doped ceria nanowires induced by nanoscratching

Nanotechnology. 2010 Jan 15;21(2):025302. doi: 10.1088/0957-4484/21/2/025302. Epub 2009 Dec 3.

Abstract

When one-dimensional nanostructures are epitaxially grown on a substrate a key goal is to control the nanowire's position and orientation. Nanoscratching of single crystalline (001)- LaAlO(3) substrates is demonstrated to be extraordinarily effective in directing the self-assembly of Ce(0.9)Gd(0.1)O(2-y) epitaxial nanowires grown by chemical solution deposition. The local anisotropic elastic strain field imposed by the indentation lines is responsible for the breaking of the pre-existing orientation energy degeneracy and selects the nanowires' orientation parallel to the lines to an extent that can reach 100%.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Anisotropy
  • Cerium / chemistry*
  • Crystallization / methods*
  • Gadolinium / chemistry*
  • Macromolecular Substances / chemistry
  • Materials Testing
  • Molecular Conformation
  • Nanostructures / chemistry*
  • Nanostructures / ultrastructure*
  • Nanotechnology / methods*
  • Particle Size
  • Solutions
  • Surface Properties

Substances

  • Macromolecular Substances
  • Solutions
  • Cerium
  • Gadolinium