Abstract
The C(2)-symmetrical "salen" ligand (+)-9 bearing two [5]ferrocenophane substituents has been prepared in five steps starting from readily available diacetylferrocene, p-hydroxybenzaldehyde and (R,R)-N,N'-diphenylethylenediamine. Reaction of (+)-9 with Mn(OAc)(3), Co(OAc)(2) ZnEt(2) or UO(2)(OAc)(2) gave the corresponding metal-complexes which were characterised by spectroscopic methods.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Benzaldehydes / chemistry
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Circular Dichroism
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Ethylenediamines / chemical synthesis*
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Ethylenediamines / chemistry*
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Ferrous Compounds / chemistry*
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Magnetic Resonance Spectroscopy
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Metallocenes
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Models, Chemical
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Molecular Structure
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Organometallic Compounds / chemical synthesis*
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Organometallic Compounds / chemistry*
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Stereoisomerism
Substances
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Benzaldehydes
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Ethylenediamines
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Ferrous Compounds
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Metallocenes
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Organometallic Compounds
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diphenylethylenediamine
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disalicylaldehyde ethylenediamine
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4-hydroxybenzaldehyde
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ferrocene