Structure studies of the nematic phase formed by bent-core molecules

Phys Rev E Stat Nonlin Soft Matter Phys. 2009 Sep;80(3 Pt 1):030701. doi: 10.1103/PhysRevE.80.030701. Epub 2009 Sep 29.

Abstract

In recent years there are several reports showing that bent-core mesogenic molecules are able to form biaxial nematic phase in which molecular rotation around the long molecular axis is strongly hindered. The x-ray pattern with azimuthally split signals at low angle region of diffraction is usually given as evidence for the biaxial nematic phase. We show experimentally and theoretically that such x-ray pattern is due to the local smectic- C fluctuations ("cybotactic" groups) in the uniaxial nematic phase.