Reversible solid-gas chemical equilibrium between a 0-periodic deformable molecular tecton and a 3-periodic coordination architecture

Deng Liu; Mian Li; Dan Li

doi:10.1039/b911955h

Reversible solid-gas chemical equilibrium between a 0-periodic deformable molecular tecton and a 3-periodic coordination architecture

Chem Commun (Camb). 2009 Dec 7:(45):6943-5. doi: 10.1039/b911955h. Epub 2009 Oct 19.

Authors

Deng Liu¹, Mian Li, Dan Li

Affiliation

¹ Department of Chemistry, Shantou University, Guangdong 515063, PR China.

PMID: 19904355
DOI: 10.1039/b911955h

Abstract

The reversible crystal transformation between a hexagonal (R3[combining macron]) porous coordination architecture [Cu(L)(2)](n) (L = 3-(pyridin-4-yl)-5-(pyrazin-2-yl)-1H-1,2,4-triazole), and a monoclinic (C2/c) molecular tecton [Cu(L)(2)(H(2)O)], was chemically implemented and structurally interpreted.